Djoser c. 2667–2648 BC
Djoser's architect Imhotep built him the Step Pyramid at Saqqara, the first large building made entirely of stone. In his own time Djoser was called by his Horus name, Netjerikhet, written in a serekh; 'Djoser' is the name later Egyptians remembered him by.
Kings this early did not use a cartouche yet: the oval around the royal name appears in the 4th Dynasty. See Sneferu's, one of the first →
Names of gods (Ra, Amun, Ptah) are written first out of respect, even when they are read later. Dates are approximate; we follow Ian Shaw (ed.), The Oxford History of Ancient Egypt (2000).